| Spain
1966 | 1965-05-05
| 1965-10-27
| 1966-07-13
| 1966-07-15
| 1966-07-20 | World Cup W/D/L: 2/0/3 | |||||||||
| Ireland
| Ireland
| Argentina
| Switzerland
| Germany
| N | Appearances | Starts | Yellow cards | Own goals | Goals | Assists
| |||
A | H | A | H | A
| |||||||||||
0-1
| 4-1
| 1-2
| 2-1
| 1-2
| |||||||||||
| José Ángel Iribar | G | ✓ | ✓ | ✓ | ✓ | 4 | 4 | 4 | 0 | 1 | 0 | 0 | |||
| Antonio Betancort | G | ✓ | 2 | 1 | 1 | 0 | 0 | 0 | 0 | ||||||
| Miguel Reina | G | 3 | 0 | ||||||||||||
| Ignacio Zoco | D | ✓ | ✓ | ✓ | ✓ | ✓ | 5 | 5 | 5 | 0 | 0 | 0 | 0 | ||
| Severino Reija | D | ✓ | ✓ | ✓ | ✓ | 5 | 4 | 4 | 0 | 0 | 0 | 0 | |||
| Gallego | D | ✓ | ✓ | ✓ | 3 | 3 | 3 | 0 | 0 | 0 | 0 | ||||
| Manuel Sanchís | D | ✓ | ✓ | ✓ | 3 | 3 | 3 | 0 | 0 | 1 | 0 | ||||
| Ferran Olivella | D | ✓ | ✓ | 5 | 2 | 2 | 0 | 0 | 0 | 0 | |||||
| Feliciano Rivilla | D | ✓ | ✓ | 5 | 2 | 2 | 0 | 0 | 0 | 0 | |||||
| Eladio Silvestre | D | ✓ | 3 | 1 | 1 | 0 | 0 | 0 | 0 | ||||||
| Luis Suárez | M | ✓ | ✓ | ✓ | 4 | 3 | 3 | 0 | 0 | 0 | 0 | ||||
| Jesús Glaría | M | ✓ | ✓ | ✓ | 5 | 3 | 3 | 1 | 0 | 0 | 0 | ||||
| Pirri | M | ✓ | ✓ | 3 | 2 | 2 | 0 | 0 | 1 | 0 | |||||
| Luis del Sol | M | ✓ | ✓ | 3 | 2 | 2 | 0 | 0 | 0 | 0 | |||||
| Adelardo | M | ✓ | ✓ | 4 | 2 | 2 | 0 | 0 | 0 | 0 | |||||
| Chus Pereda | M | ✓ | 1 | 1 | 1 | 0 | 0 | 3 | 0 | ||||||
| Josep Fusté | M | ✓ | 3 | 1 | 1 | 0 | 0 | 1 | 0 | ||||||
| José Ufarte | F | ✓ | ✓ | ✓ | 5 | 3 | 3 | 0 | 0 | 0 | 0 | ||||
| Marcelino | F | ✓ | ✓ | ✓ | 5 | 3 | 3 | 0 | 0 | 0 | 1 | ||||
| Carlos Lapetra | F | ✓ | ✓ | ✓ | 5 | 3 | 3 | 0 | 0 | 1 | 0 | ||||
| Paco Gento | F | ✓ | ✓ | 3 | 2 | 2 | 0 | 0 | 0 | 1 | |||||
| Joaquín Peiró | F | ✓ | ✓ | 3 | 2 | 2 | 0 | 0 | 0 | 0 | |||||
| Amancio | F | ✓ | ✓ | 3 | 2 | 2 | 0 | 0 | 1 | 0 | |||||
| Vicente Guillot | F | ✓ | 1 | 1 | 1 | 0 | 0 | 0 | 0 | ||||||
| Manager: | José Villalonga
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